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Calculating the value of Kc.

Updated: Jul 12, 2021


 

Key points to be noted:


* If you see [ ] = concentration of an element

*You only use Kc values in an equilibrium question.

* The units are always different for every reaction so don't memorize the units. You will need to work them out in an exam.


General formula:


You must learn this formula as it will not be provided in the exam.


Rules to remember when calculating Kc value:

  • You must raise them to the power of their moles.

  • You must remember to put square brackets around your reactants and products to show the examiner you are talking about concentration.

  • If you change one variable, you must change the other reactant/product.

  • Kc, we cannot change in a chemical reaction.

  • Every Kc value has its own unique units.


 

For example:

Calculate the Kc for this reaction below using the information provided.



= 1 moldm³ at equilibrium

= 3 moldm³ at equilibrium


Method:

  1. Substitute the provided information into the Kc formula.

  2. Raise the powers according to the number of moles.

  3. Solve the equation to find Kc.

Write the expression:







Full working out:

Kc = (3)² / 1 = 9.0 moldm³

Unit manipulation for Kc:

  • Every Kc value has its own unique units which are different for every reaction.

  • To find the units of Kc, start by listing out the units like so...



​**Remember, the best way of getting better at calculating Kc values is to do some past paper questions. **

Value and Kc meaning:

  • If Kc is very large (about 1000), we will have mostly product species present at equilibrium which will give a forward direction to make the product.

  • If Kc is very small ( about 0.001), we will have mostly reactant species present at equilibrium which will give a backward direction to make the reactant.

  • If Kc is between 0.001 and 1000, we will have a significant concentration of both reactant and product species present at equilibrium.


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